Process for preparing lubrication varnishes for metals

专利摘要:
, THE METHOD OF OBTAINING LUBRICANT VARNISHES FOR METALS by dispersing graphite fluoride in water in the presence of a surfactant, which differs from the fact that, in order to increase the adhesion and antifriction properties of lubricating varnishes, 5-50% by weight of fluoride is dispersed in water graphite, as a surfactant use 5-15 wt.% sodium salt of the condensation product of naphthalenesulfonic acid with formaldehyde and the resulting aqueous dispersion is mixed with a mixture of graphite fluoride in glycerol in their mass ratio 1: 2 to obtain a total mass ratio of graphite fluoride to glycerol CO 0.5-0.8.
公开号:SU1075983A3
申请号:SU803004906
申请日:1980-11-12
公开日:1984-02-23
发明作者:Шош Элизабет；Ребиффе Мишель
申请人:Продюи Шимик Южин Кюльман (Фирма)；
IPC主号:

专利说明:

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This invention relates to a process for the preparation of lubricating lacquers for metals.
A method is known for producing lubricating lacquers for metals by dispersing a solid lubricant, such as molybdenum disulfide, graphite, polytetrafluoroethylene in EPOXY, phenolic or polyvinyl fl5.
The closest in technical essence to the present invention is a method of producing lubricating lacquers for metals by dispersing in water 10% by weight of graphite fluoride in the presence of 20% by weight of the surfactant substance n-alkylphenylpolyoxyalkylene ether C 2 3.
However, a lubricating varnish obtained in a known manner has low adhesion and antifriction properties.
The adhesion of varnishes to meteslichesky surfaces depends on many factors:
roughness of the metal surface to be treated, which itself depends on the method of polishing. Thus, grinding allows to obtain a roughness of 0.10, 4 microns ((It), whereas in sand blasting it is difficult to obtain a roughness of 1 micron;
granulometry of solid lubricant, which may vary in the range of 10-1 microns, depending on the method of preparation and grinding /
the nature of the metal surface to be lubricated; steel grade (stainless steel, heat resistant steel), cast iron, aluminum cast iron, tungsten carbide, etc.
The grain size of a solid lubricant should be closely related to the roughness of the metal surface. The smaller the roughness, the smaller the size of the particles of the solid lubricant must be in order to achieve good adhesion of varnish to metal.
The aim of the invention is to develop a method for producing lubricating varnishes with enhanced adhesive and anti-friction properties.
The goal is achieved by the fact that according to the method of producing lubricating varnishes for metals, 550% by weight of graphite fluoride is dispersed in water in the presence of 5-15% by weight of the surfactant sodium salt of the condensation product of naphthalene sulfonic acid with formaldehyde, the resulting aqueous dispersion is then mixed with a mixture of fluoride GE) afit with glycerin in their mass ratio of 1: 2 to obtain the total mass ratio of fluoride
graphite to glycerol in the range of 0.5-0.8.
Graphite fluorides are solid lubricants that have numerous advantages over molybdenum disulfide. They correspond to the general formulas {With which X can vary in the range of 0.8-1.2; m - may be different.
Varnishes containing 2 ma.h. glycerol and 1 ma.ch. graphite fluoride (with a F / CX ratio of 0.9) with an average grain size of 1 µm, adheres firmly after heating to 250 ° C to steel products, for example, car engines, and chromium-chromium-alloyed m .
Stainless steels have the lowest adhesion. Such poor adhesion is due, on the one hand, to the nature of the metal, and, on the other hand, to the fact that the mixture of glycerol and fluoride of graphite is a paste and forms films of excessive thickness. If this mixture is diluted with water, lacquer is obtained to make it less viscous, which quickly delaminates and, therefore, is not suitable for long-term storage. In addition, the adhesion of such varnish to metals is completely inadequate.
Aqueous dispersions of graphite fluoride can be prepared by grinding, for example, 20% by weight of graphite fluoride with a particle size of 5 μm in the presence of 70% by weight of water and 10% by weight of sodium salt of a naphthalene sulfonic acid condensation product with formaldehyde. The final particle size of the graphite fluoride in the dispersion is approximately 1 µm.
If such a dispersion is sprayed onto ferrous metals and aluminum, then after sintering at 250 ° C, it forms a homogeneous film with low lubricity and not resistant to water: when tested by water, drop by drop a steel plate coated on it such a film is a quick peeling and peeling of the film.
If glycerin is introduced into the aqueous dispersion of graphite fluoride in such an amount that the fluoride ratio is
5 of graphite: glycerin was equal to 0.4 and this composition was sputtered onto aluminum or steel, after sintering a very heterogeneous film with low adhesiveness was obtained.
On the other hand, if powdered graphite thoride is directly mixed, glycerin and an aqueous surfactant solution will produce compositions which, when applied to aluminum and dried at a temperature
5 form varnishes with good adhesion.
but not able to withstand the test of home-i drop by drop. However, it was found that if a mixture of glycerin and powdered graphite fluoride is prepared separately and a water dispersion of graphite fluoride stabilized with a surfactant is added to the mixture, then compositions are obtained which, after drying for 1 hour at 250 ° C, form bright varnishes characterized by very good adhesion to metals of all types and excellent resistance to water. These compositions can be easily applied by spraying and produce very thin films, 4-5 microns thick, with a great lubricating and lubricating ability. In compositions, the choice of binder that hardens at a high temperature is of decisive importance. If, instead of 1Glycerol, a sugar syrup is taken, a lubricating composition is obtained which does not spread and is not sprayed. The selection of a dispersant used as a stabilizer for the aqueous dispersion of graphite fluoride is also important. If instead of using the sodium salt of the condensation product of naphthalene sulfonic acid with formaldehyde, to use other surfactants, then get varnishes that do not have the required adhesion.
The surfactant is hereinafter referred to as sodium salt powder.
Example 1.A. Thoroughly mix 100. graphite fluoride, which has x 0.9, and the particle size is 1 micron, from 200 May, h. glycerol,
B. Ready t 100 mach. stabilized water dispersion of graphite fluoride by dispersing
20% by weight of graphite fluoride in 70% by weight of water and 10% by weight of powdered sodium salt.
C. To 50 parts A of the mixture A is added 50 hours to the dispersion B and homogenized. Thus obtained lubricating composition with a ratio of graphite fluoride
to glycerol 0.8 (composition).
D. To 62 parts of mixture A are added 38 hours of dispersion B and homogenize. A lubricant composition with a graphite fluoride to glycerol ratio of 0.68 (composition 2) is thus obtained. .
E. To 86 parts of mixture A are added 14 hours of dispersion B and homogenized. Thus, a lubricant composition is obtained in which the ratio of graphite fluoride to glycerin is 0.548 (composition 3).
Example 2. A. A mixture of 100 parts by weight is prepared as in Example 1. graphite fluoride with 200 wt.h. glycerol.
Vf Ready t 100 wt.h. stabilized aqueous fluoride dispersion
graphite, grinding 5 wt.% graphite fluoride in 90 wt.% water in the presence of 5 wt.% powder of sodium salt.
C. To 20 parts of mixture A, 80 parts of dispersion B are added and homogenized. In this way, a lubricant composition is obtained, having a mass ratio of graphite fluoride to glycerol equal to 0.80. (composition 4).
Example 3. A. Prepared
0 as in example 1, a mixture of 100 wt.h. graphite fluoride about 200 wt.h. glycerol.
B. Ready t 100 wt.h. stabilized water dispersion of graphite fluoride, grinding 50 wt.% fluoride
5 graphite in 35% by weight of water in the presence of 15% by weight of sodium salt powder.
C. To 75 parts of mixture A are added 25 parts of dispersion B and homogenized. In this way, a lubricant composition is obtained,
0 having a mass ratio of graphite fluoride to glycerin, equal to 0.75
(COLLECTION 5). .
Compositions 1–5 are sprayed onto plates of ordinary steel, stainless steel and aluminum with varying degrees of watering so as to obtain, after heating at 250 ° C for 1 hour, lacquers with a thickness of 4–5 µm. In all cases, the adhesion of varnish to metal is recognized.
0 good or very good and the film formed on the metal surface withstands the test of water drop by drop well.
The lubricity of compositions 1-5 is measured using a ball-plane maiii, which allows re, friction coefficient as a function of temperature. The disc from Art. XC 38 is polished to a given roughness and coated with test subjects.
0 product. This disk, rotating at a constant speed, is subjected to pressure, which produces a stationary ball of art. 100 Sat. For comparison, under the same conditions, the lubricity of a simple mixture of 2/1 glycerol and fluoride graphite (A in example 1) and the lubricity of an aqueous dispersion of graphite fluoride (B in example 1) are measured.
0
The tests were carried out at a slip rate of 0.15 m / s, a disk roughness of 0.1-0.2 µm and an applied load of 1 DN. . The test results of the composition 1-5 mixture A and dispersion B,
5 obtained in example 1 are presented in the table.
The stability of friction is considered good, if in the process of measuring the change in the coefficient of friction (JEM) is less than or equal to 0.01, it is considered average if the DS is 0.02, poor if it is 0.02.
As can be seen from the results ispataniya (table) compositions 1-5, obtained by the proposed method, provide
five
Good and satisfactory lubricating properties, having 4CFiO, 02, while
time as the dispersion In DSG 6 2 (0.03-0.08).
The composition 1 described in example 1 is used to improve the lubrication of pillows consisting of a steel strip coated with brass balls sintered and impregnated with polytetrafluoroethylene. One layer is enough to obtain, after drying at 250 ° C for 1 h, a very good varnish. If, for comparison, a simple blend A is used (Example 1), it is necessary to apply several layers, and in
.Table continuation
the resulting lacquer does not have adhesion.
Composition 1, described in example 1, is used to lubricate an instrument made from aluminum that is intended for the manufacture of articles made of filled polyurethane. This device consists of a cylindrical ring in which a tight fitting cylinder slides. Composition 1 is sprayed onto the inner surface of the ring and
per cylinder forms a lacquer with good adhesion and lubricity, while mixture A (example 1 forms a lacquer after sintering that does not have adhesion.
Varnishes obtained according to the proposed method can also be used to lubricate products exposed to very high temperatures. Thus, the compound 1 described in example 1 was sprayed onto products made of heat-resistant steel used in a solid installation and exposed to a temperature of 5006 ° C and a splash of solder. After drying, composition 1 forms a lacquer with a good
adhesion resistant in harsh environments.
If a tungsten carbide product, represented by a polished mirror, with which it is very difficult to achieve adhesion of varnish, is applied a layer of mixture A (example 1), then there is a complete absence of adhesion of varnish to the product. In contrast, composition 1 forms a lacquer with good adhesion ..
0
Thus, the lacquers obtained by the proposed method provide high adhesion and anti-friction properties.
five

权利要求:
Claims (1)
[1]
* “METHOD FOR PRODUCING LUBRICANTS FOR METALS by dispersing graphite fluoride in water in the presence of a surfactant, characterized in that, in order to increase the adhesion and antifriction properties of lubricants; ny varnishes, disperse in water
5-50 wt.% Graphite fluoride, 5-15 wt.% Sodium salt of the product of condensation of naphthalene sulfonic acid with formaldehyde is used as a surfactant and the resulting aqueous dispersion is mixed with a mixture of graphite fluoride with glycerin in their mass ratio 1: 2 to obtain the total the mass ratio of graphite fluoride to glycerin is 0.5-0.8.

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引用文献:

---

公开号 | 申请日 | 公开日 | 申请人 | 专利标题

---

---

CA499584A|1954-01-26|J. Morway Arnold|Lubricant|

---

DE274510C|1900-01-01|

---

US905649A|1906-08-20|1908-12-01|William Humphrey Knowles|Lubricant.|

---

DE278510C|1914-04-01|

---

US2083176A|1935-06-29|1937-06-08|Acheson Colloids Corp|Lubrication of rubber|

---

US2176879A|1937-11-20|1939-10-24|Acheson Colloids Corp|Method of disintegrating, dispersing and stabilizing graphite and product|

---

US3071543A|1960-07-12|1963-01-01|Mcgee Chemical Company Inc|Solid lubricant containing compositions|

---

US3341454A|1963-02-25|1967-09-12|Hodson Corp|Lubricant composition|

---

JPS49964B1|1968-05-27|1974-01-10|Nippon Carbon Co Ltd|

---

JPS4919750B1|1970-12-21|1974-05-20|

---

JPS5223983B2|1972-07-07|1977-06-28|

---

JPS54105651A|1978-02-07|1979-08-18|Mitsubishi Heavy Ind Ltd|Pipe expanding lubricant|

---

JPS54125366A|1978-03-24|1979-09-28|Hitachi Funmatsu Yakin Kk|Lubricant for plastic working|US4770797A|1986-03-31|1988-09-13|Allied-Signal Inc.|Carbon fluoride chloride lubricant|

---

US4746248A|1987-02-19|1988-05-24|E. I. Du Pont De Nemours And Company|Anchor bolt assembly|

---

JPH01127920U|1988-02-25|1989-08-31|

---

JPH057438B2|1988-05-26|1993-01-28|Asahi Garasu Kk|

---

US4984938A|1988-08-25|1991-01-15|H&S Machine & Supply Company, Inc.|Coated washer for an anchor bolt system|

法律状态:

优先权:

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申请号 | 申请日 | 专利标题

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FR7927887A|FR2469438B1|1979-11-13|1979-11-13|

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